Lee Kang-hoon (Shin Ha-kyun), who graduated from the top medical school, works at the top hospital, and is the top neurosurgeon around. Basically, he’s Brain No. 1. (And he works on brains, too!) He has ambitions to become the director at his university hospital. He is obsessed with success, which is probably both his greatest flaw and strength, since it makes him steely and fierce.
However, once he meets his sunbae Kim Sang-chul (Jung Jin-young), the prickly genius doctor and world famous neurologist, he turns over a new leaf and becomes a sincere doctor. Seo Joon-suk (Jo Dong-hyuk) is a doctor and will become Lee Kang-hoon’s rival. Yoon Ji-hye (Choi Jung-won) is also a neurosurgeon who grew up in an ordinary family. She is extremely strict in matters of work and study, but has a warm bedside manner with her patients
天才神經外科醫師李康勳，個性狂妄霸道，對他而言，醫學只是一種技術，不帶任何的情感。在同家醫院工作的醫師尹智慧無法忍受康勳對病患總是冷冰冰的惡劣態度，忍不出開口糾正他的行為，兩人處處針鋒相對，互不相讓。然而康勳精湛的醫術，卻也讓智慧悄悄地折服傾心……
當暗戀智慧多年、同時也是康勳在醫界的競爭對手徐俊錫，發現智慧與康勳間的曖昧情愫，他會使出什麼樣的手段來擊敗康勳？向來自視甚高、目中無人的康勳，該如何在這場白色巨塔的戰爭中，發現自己的真心？當他冰冷的心漸漸被智慧的熱情融化之際，他又會如何一步步從一位醫病的醫師，變成一位醫心的仁醫？
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