桃花县捕快之女唐小山不喜读书，一心想成为一代女捕快。为了父亲，唐小山替好友赴百花书院参加才女考试。去往途中，与身负朝廷密务的英承墨结下梁子，不想入书院后发现英承墨竟是自己的大先生。唐小山与才女云集的书院生活格格不入，千方百计想离开，却又一次次意外留下，甚至与英承墨一起被卷入一场惊天大阴谋。唐小山这一场仗义冒险，从荒野丫头成长为山河女子，并收获一段与英承墨之间的欢喜记事，温暖彼此，携手共进。
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