In 1985 a chemist looking at stardust, paired with one searching for brand new materials, stumbled across what science said could not exist – a third form of carbon. They named the soccer ball-shaped molecules "Buckminsterfullerene" after the architect who invented the geodesic dome. Today "Buckyballs," as the molecules are playfully known, are revolutionizing chemistry and promise countless technological applications. NOVA traces this remarkable tale of serendipity in scientific discovery.