Dermot interviews Amy Winehouse and Pete Doherty about teaming up to release a new charity single together. Once he finally gets them talking, Amy can only call out for her husband, Blake, and Pete seems oblivious to his break-up with Kate Moss. They then spend the remainder of the part boasting about their drug taking exploits. Pete and Amy then appear to be in some confusion as to what an Anti-Drug campaign is, and the two perform their new single, which is revealed to be a cover of Grange Hill's 'Just Say No'.